The Use of Weissler Method for Scale-Up a Kraft Pulp Oxidation by TEMPO-Mediated System from a Batch Mode to a Continuous Flow-Through Sonoreactor

The efficiency of cellulose oxidation mediated by the 4-acetamido-TEMPO radical under ultrasonic cavitation was investigated using two ultrasonic systems: a batch lab scale ultrasonic bath with a glass reactor and a semi-continuous flow-through sonoreactor. The main objective was to explore the possibility of scaling up the production of oxidized cellulose under ultrasound, from a lab scale process to a pilot plant process, which served as a precursor for producing nanofibrils cellulose. It was found that under acoustic cavitation, the efficiency of TEMPO-mediation oxidation of native cellulose was significantly improved, particularly in the flow-through sonoreactor. In comparison with the glass reactor, the flow-through sonoreactor reduce the applied energy by 88% while increasing 7.8 times the production rate of radicals. These results enable a possibility of producing oxidized fibers for industrial applications.

► KI dosimetry can be used to transfer batch mode reaction to a semi-continuous mode.
► Flow-through sonoreactor was more efficient on acoustic cavitation.
► Flow-through sonoreactor decreases the applied energy.
► Cellulose oxidation reaction can be applied in continuous mode for the industrial applications.