Mechanistic investigation of the sonochemical synthesis of zinc ferrite

In this investigation, an attempt has been made to establish the physical mechanism of sonochemical synthesis of zinc ferrite with concurrent analysis of experimental results and simulations of cavitation bubble dynamics. Experiments have been conducted with mechanical stirring as well as under ultrasound irradiation with variation of pH and the static pressure of the reaction medium. Results of this study reveal that physical effects produced by transient cavitation bubbles play a crucial role in the chemical synthesis. Generation of high amplitude shock waves by transient cavitation bubbles manifest their effect through in situ micro-calcination of metal oxide particles (which are generated through thermal hydrolysis of metal acetates) due to energetic collisions between them. Micro-calcination of oxide particles can also occur in the thin liquid shell surrounding bubble interface, which gets heated up during transient collapse of bubbles. The sonochemical effect of production of OH radicals and H2O2, in itself, is not able to yield ferrite. Moreover, as the in situ micro-calcination involves very small number of particles or even individual particles (as in intra-particle collisions), the agglomeration between resulting ferrite particles is negligible (as compared to external calcination in convention route), leading to ferrite particles of smaller size (6 nm).

► An attempt to establish physical mechanism of sonochemical synthesis of zinc ferrite.
► Crucial role of physical effects produced by transient cavitation bubbles.
► In-situ microcalcination by energetic collisions between of metal oxide in shock waves.
► Micro-calcination also possible in the thin liquid shell surrounding bubble.
► Smaller size of ferrite particles with micro-calcination as compared to bulk calcination.