The “periodic table” of benzotriazoles: Uranium(VI) complexes

• Benzotriazoles have been employed as ligands in uranium(VI) chemistry.
• Hexagonal bipyramidal uranyl complexes have been structurally characterized.
• The complexes have been studied by Raman, IR and 1H-NMR spectroscopies.

The first employment of benzotriazoles in uranium(VI) chemistry has led to uranyl complexes with interesting structures and spectroscopic properties; the reactions of uranyl nitrate with 5,6-dimethylbenzotriazole give two products depending on the reactants' molar ratio.

The first employment of simple benzotriazoles in U(VI) chemistry gives mononuclear uranyl complexes with interesting structural and spectroscopic features.Figure optionsDownload as PowerPoint slide