کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1301612 1498918 2016 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Two open-framework zinc phosphites constructed from different secondary building units
ترجمه فارسی عنوان
دو فسفیت روی فتوکپی باز فشرده ساخته شده از واحدهای ساختمان ثانویه دیگر
کلمات کلیدی
مواد چارچوب باز، فسفیت روی، واحد ساختمان ثانویه، توپولوژی، جذب گاز
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
چکیده انگلیسی


• New metal phosphites are constructed from different secondary building units.
• Open-framework structures display bnn and dia topologies.
• A hypothetic 4-connected net is proposed.

Presented here are two new zinc phosphites, formulate as Zn3(dabco)2(HPO3)3 (1, dabco = 1,4-diazabicyclo[2·2·2]octane), and H2pmdeta ⋅ Zn3(HPO3)4 (2, pmdeta = N,N,N′,N″,N″-pentamethyldiethylenetriamine). Compound 1 has 12-membered-ring (12 MR) channels with a 5-connected bnn topology containing 4 = 1 secondary building units. Compound 2 has multidirectional 10 MR channels with a pcu topology constructed from 6*1 secondary building units. The gas adsorption and fluorescent properties of compound 1 were also investigated.

Two open-framework zinc phosphites are constructed from 4 = 1 and 6*1 secondary building units, respectively. For the first time, the 6*1 units are organized into a three-dimensional structure in metal phosphite systems. A hypothetic 4-connected framework is proposed by converting 6*1 units into D4R units.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 72, October 2016, Pages 96–99
نویسندگان
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