کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1301688 | 1498951 | 2014 | 4 صفحه PDF | دانلود رایگان |
• One pot synthesis of complexes from tmeda, Pd(II) and pyridine ligands
• Ligand exchange reactions (LER) around Pd(II)
• Application of the LER in the synthesis
One-pot synthesis of self-assembled heteroleptic complexes of general formula [Pdx(tmeda)x(L)y](NO3)2x is achieved by combining required amount of tmeda, a chosen ligand L and Pd(NO3)2 under suitable reaction conditions. The strategy is devised using our understanding of a special variety of ligand exchange reactions (LER) around palladium(II) centers as modeled in this work. The one-pot synthesis technique is thus considered as an application of the unique LER.
One-pot synthesis of self-assembled heteroleptic complexes of general formula [Pdx(tmeda)x(L)y](NO3)2x is achieved by combining required amount of tmeda, a chosen ligand L and Pd(NO3)2 under suitable reaction conditions.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 39, January 2014, Pages 75–78