کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1301745 1498943 2014 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Helical structures in a lithium hexacyanocobaltate-based three-dimensional metal–cyanide framework
ترجمه فارسی عنوان
ساختارهای مارپیچی در یک چارچوب متالایانای سه بعدی بر اساس هگزاسیانوکوبالطبی لیتیوم
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
چکیده انگلیسی


• lithium hexacyanocobaltate-based inorganic-organic hybrid compound
• three-dimensional metal-cyanide framework
• anionic chiral 3D structure composed of helical chains
• rich hydrogen bonds among guest molecules and anionic framework

Inorganic–organic hybrid compound (C3H5N2)2(H2O){[Li(H2O)][Co(CN)6]} was synthesized by the reaction of Li3[Co(CN)6] with imidazolium chloride in aqueous solution. It crystallizes in the chiral orthorhombic space group P212121 at 293 K. The anionic chiral 3D structure is composed of helical chains based on the inorganic {[Li(H2O)][Co(CN)6]} building blocks. Imidazolium cations and crystallization water molecules reside in the voids of the anionic framework through rich hydrogen bonds.

Anionic chiral 3D structure of (C3H5N2)2(H2O){[Li(H2O)][Co(CN)6]} is composed of helical chains based on the inorganic {[Li(H2O)][Co(CN)6]} building blocks. Imidazolium cations and crystallization water molecules reside in the voids of the anionic framework through rich hydrogen bonds.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 47, September 2014, Pages 1–4
نویسندگان
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