Hydrothermal synthesis and characterization of a novel supramolecular hybrid based on Keggin and Cu(I) complex

• [Cu(4,4′bipyH)3(4,4bipy)][HPW12O40]2.12H2O were sythesized using hydrothermal method.
• The effect of pH of reaction media is studied.
• Purple crystals were analysed using IR, UV and X-ray diffraction.
• Molecule extends in 3D through hydrogen bonding.

A novel inorganic–organic hybrid molecule, [Cu(4,4′bipyH)3(4,4bipy)][HPW12O40]2.12H2O (1), has been hydrothermally synthesized and characterized by IR spectra, TG and single crystal X-ray diffraction analyses. Structural analysis reveals that the novel compound 1 composed of two Kegging polyoxoanion connected with Cu complex fragment forming a big molecule that extends in 3D via hydrogen bonding.

Structure of [Cu(4,4′bipyH)3(4,4bipy)][HPW12O40]2.12H2O consists of two Kegging polyoxoanion connected with Cu complex fragment forming a big molecule that extends in 3D via hydrogen bonding.Figure optionsDownload as PowerPoint slide