کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1301865 | 1498953 | 2013 | 6 صفحه PDF | دانلود رایگان |
• Unexpected ortho-metalation led to a ruthenium(II)–PCNHCC− complex.
• ortho-Metalated catalyst exhibits slow initiation kinetics.
• Catalyst derived from ruthenium(II)–PCNHC complex is active at room temperature and in air using unpurified solvent.
We have prepared and characterized two ruthenium(II) complexes supported by phosphine-functionalized N-heterocyclic (NHC) ligands. One of the complexes (2a) underwent ortho-metalation of the N-phenyl moiety giving rise to a tridentate PCNHCC− coordinating ligand whereas 2b bears an N-mesityl group in order to prevent C–H activation of the aryl ring thereby enforcing a PCNHC bidentate binding mode. Both 2a and 2b were shown to catalyze transfer hydrogenation of ketones at 82 °C in 2-propanol in the presence of KOtBu albeit with vastly different catalytic activities. Catalytic transfer hydrogenation by 2b was shown to proceed at room temperature and in air using unpurified 2-propanol as solvent and hydrogen donor. Time studies revealed unique kinetic profiles for the two precatalysts; this may shed light on the difference in their catalytic activities.
Two ruthenium(II) complexes supported by phosphine-functionalized N-heterocyclic carbene ligands have been prepared, characterized and evaluated as catalysts for transfer hydrogenation of ketones.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 37, November 2013, Pages 138–143