کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1301871 | 1498953 | 2013 | 4 صفحه PDF | دانلود رایگان |

• Hydrothermal in situ HATAZ ligand synthesis
• New Zn(II) coordination polymer based on pbdc and ATAZ
• It emits intense luminescence at room temperature.
A new compound, namely [Zn1.5(pbdc)(ATAZ)(OH)]n (1 H2pbdc = terephthalic acid, HATAZ = 3-amino-1,2,4-triazole), has been obtained by in situ aminotriazole ligand synthesis and characterized by elemental analysis, thermal analysis, as well as single crystal and powder X-ray diffraction analysis. Compound 1 exhibits a 3D pillar–layer framework based on Zn(II)-aminotriazole layers and pbdc pillars, which can be simplified into a 2-fold interpenetrated pcu topological network. Interestingly, two ATAZ ligands and two OH− ligands bridge three Zn(II) ions together, giving rise to a new trinuclear {Zn3(ATAZ)2(OH)2} subunit. In addition, the luminescent and thermal stability properties for the title compound have also been studied.
Presented here is a new luminescent Zn(II) coordination polymer, namely [Zn3(pbdc)(ATAZ)(OH)2]n (1 H2pbdc = terephthalic acid, HATAZ = 3-amino-1,2,4-triazole), which was constructed from H2pbdc and in situ generated HATAZ ligands.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 37, November 2013, Pages 162–165