کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1301909 1498954 2013 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Syntheses, structures and magnetic properties of one family of 3d–4f chiral metal-organic frameworks (MOFs) based on D(+)-camphoric acid
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Syntheses, structures and magnetic properties of one family of 3d–4f chiral metal-organic frameworks (MOFs) based on D(+)-camphoric acid
چکیده انگلیسی


• Eleven chiral 3d-4f MOFs have been synthesized and characterized.
• They exhibit unique 6-connected frameworks.
• The magnetic behaviors have been systematically investigated.

The hydrothermal reactions of D(+)-camphoric acid (D-H2Cam) and 1,10-phenanthroline (phen)/2,2′-bipyridine (2,2′-bipy) with the corresponding metal salts gave rise to eleven chiral 3d–4f heterometallic metal-organic frameworks (MOFs). Single-crystal X-ray diffraction measurements reveal that the crystal structures are isostructural, crystallizing in the orthorhombic space group P212121 and they exhibit unique three-dimensional chiral 6-connected frameworks involving 1D zigzag chains aligned parallel to the a axis and the 2D wave-like lanthanide layers, with the Schläfli symbol (49 · 66). Moreover, we have systematically investigated the magnetic behaviors of partial compounds.

Eleven chiral 3d-4f Metal-Organic Frameworks constructed from D(+)-camphoric acid have been synthesized. The crystal structures exhibit unique three-dimensional chiral 6-connected frameworks. The magnetic behaviors have been systematically investigated.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 36, October 2013, Pages 63–67
نویسندگان
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