کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1301918 | 1498954 | 2013 | 4 صفحه PDF | دانلود رایگان |
• Neutral rhenium(I)-based mixed-ligands tetranuclear complex.
• Four mononuclear complex units are arranged spatially in a molecule.
• Mononuclear complex contains Re(CO)3, pyridinyl and 2-(benzoxazol-2-yl)phenolate.
The reaction of Re2(CO)10 with 2-(benzoxazol-2-yl)phenol (HL) and 1,2,4,5-tetrakis(4-pyridylvinyl)benzene (L2) gives a heteroleptic tetranuclear complex, [((fac-Re(CO)3)L)4(L2)] 1. The corner of 1 comprises four spatially arranged mononuclear units.
The reaction of Re2(CO)10 with 2-(benzoxazol-2-yl)phenol (H2L) and 1,2,4,5-tetrakis(4-pyridylvinyl)benzene (L2) gives a heteroleptic tetranuclear complex, [((fac-Re(CO)3)L)4(L2)] 1. The corner of 1 comprises four spatially arranged mononuclear units.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 36, October 2013, Pages 109–112