کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1301924 | 1498954 | 2013 | 4 صفحه PDF | دانلود رایگان |
• 4-Fold interpenetrating 3D silver(I) coordination polymer has been synthesized.
• Bis(4-pyridyl)cyclotetramethylsilane acts as a potential interesting bridging ligand.
• The compound is the first example of a binodal 3,3-connected (82∙10)2-ete framework.
• The compound displays blue-light emitting properties at room temperature.
Self-assembly of AgClO4 with bis(4-pyridyl)cyclotetramethylsilane (L) produces a 4-fold interpenetrating 3D coordination polymeric framework consisting of [Ag5(L)7(CH3CN)2](ClO4)5∙2CH3CN (1). The topological analysis indicates that the compound is the first example of a binodal 3,3-connected (82∙10)2-ete net topology. Its thermal behavior and photoluminescent properties have been investigated.
Self-assembly of AgClO4 with bis(4-pyridyl)cyclotetramethylsilane (L) produces a 4-fold interpenetrating 3D coordination polymeric framework consisting of [Ag5(L)7(CH3CN)2](ClO4)5∙2CH3CN, which is the first example of a binodal 3,3-connected (82∙10)2-ete framework, according to topological analysis. Its thermal behavior and blue-light emitting properties have been investigated.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 36, October 2013, Pages 133–136