کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1301933 1498954 2013 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Structure and physical properties of a hydrogen-bonded framework based on carboxyl-substituted TTF ligand and Mn(ClO4)2
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Structure and physical properties of a hydrogen-bonded framework based on carboxyl-substituted TTF ligand and Mn(ClO4)2
چکیده انگلیسی


• TTF-based carboxylic acid L which is soluble has been synthesized and characterized.
• Optimized conformation and orbital diagram of L has been calculated with DFT.
• An interesting 3D supramolecular network based on L and Mn(ClO4)2 is synthesized.

The well-soluble tetrathiafulvalene carboxylic derivative [Bu4N]2[TTF(COOH)2(COO)2] (L) has been used to create the interesting 3D supramolecular network [Mn(H2O)4(CH3OH)2][TTF(COOH)2(COO)2] (1), driven by O–H⋅⋅⋅O interaction. The absorption spectra and electrochemical behavior of L and 1 have been discussed. Optimized conformation and molecular orbital diagram of L have been calculated with density functional theory.

A well-soluble TTF–carboxylic derivative L has been synthesized. By ion exchange reaction, an interesting 3D supramolecular network 1 was obtained. Their electrochemical and absorption behaviors have been measured and analyzed. The results suggest that the TTF–carboxylic ligand is useful for building intriguing supramolecular systems.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 36, October 2013, Pages 170–173
نویسندگان
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