کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1301933 | 1498954 | 2013 | 4 صفحه PDF | دانلود رایگان |

• TTF-based carboxylic acid L which is soluble has been synthesized and characterized.
• Optimized conformation and orbital diagram of L has been calculated with DFT.
• An interesting 3D supramolecular network based on L and Mn(ClO4)2 is synthesized.
The well-soluble tetrathiafulvalene carboxylic derivative [Bu4N]2[TTF(COOH)2(COO)2] (L) has been used to create the interesting 3D supramolecular network [Mn(H2O)4(CH3OH)2][TTF(COOH)2(COO)2] (1), driven by O–H⋅⋅⋅O interaction. The absorption spectra and electrochemical behavior of L and 1 have been discussed. Optimized conformation and molecular orbital diagram of L have been calculated with density functional theory.
A well-soluble TTF–carboxylic derivative L has been synthesized. By ion exchange reaction, an interesting 3D supramolecular network 1 was obtained. Their electrochemical and absorption behaviors have been measured and analyzed. The results suggest that the TTF–carboxylic ligand is useful for building intriguing supramolecular systems.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 36, October 2013, Pages 170–173