کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1302051 | 1498973 | 2012 | 4 صفحه PDF | دانلود رایگان |
A new metal-organic framework (MOF), [Zn3(4,4’-ADB)3(BIB)2]n (1) has been synthesized based on mixed bridging ligands BIB and 4,4’-ADB (BIB = 1,4-bis(2-methyl-imidazol-1-yl) butane, 4,4’-ADB = azobenzene-4,4’-dicarboxylica acid). This MOF is a 3D structure with trinuclear zinc(II) clusters as SBU. The trinuclear zinc (II) clusters of line style feature zincs in two tetrahedral and one octahedral coordination environments. The MOF exhibits a 3-fold interpenetrated framework with 36·418·53·6 topology, which reduces the effective void but stabilizes the compound.
One new coordination polymer [Zn3(4,4’-ADB)3(BIB)2]n (1) has been synthesized. It exhibits a 3D structure with trinuclear zinc(II) clusters of line style as the secondary building unit (SBU), and displays a 3-fold interpenetrated framework.Figure optionsDownload as PowerPoint slideHighlights
► [Zn3(4,4’-ADB)3(BIB)2]n (1) has been synthesized.
► It is a new 3-fold interpenetrated framework.
► It contains two types of Zn atoms that trinuclear zinc(II) cluster as SBU.
Journal: Inorganic Chemistry Communications - Volume 17, March 2012, Pages 30–33