کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1302083 | 1498973 | 2012 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: An unprecedented [Cu7I4]3 + cationic cluster-based metal–organic framework (MOF) including 1D nanochannels An unprecedented [Cu7I4]3 + cationic cluster-based metal–organic framework (MOF) including 1D nanochannels](/preview/png/1302083.png)
A new cationic copper–iodine based metal–organic framework compound, [Cu7I4L3(H2O)]n (1) (L = 5-(3-pyridyl)tetrazole), has been synthesized by solvothermal method. X-ray analysis shows that compound 1 is a 3-D metal–organic framework constructed by the L ligands linking new discrete (Cu7I4)3 + cationic clusters, which has an uncommon (3, 9)-connected gfy topological network including 1D hexagonal nano-channels.
Presented here is a new 3D metal-organic framework [Cu7I4L3(H2O)]n (1) (L = 5-(3-pyridyl)tetrazole), has been synthesized by solvothermal method. Structural analysis shows that compound 1 is an interesting (Cu7I4)3 + cluster-based metal–organic framework (MOF) with uncommon (3, 9)-connected gfy topology.Figure optionsDownload as PowerPoint slideHighlights
► Unprecedented cationic [Cu7I4]3 + cluster was trapped by solvothermal synthesis of an anionic-tetrazolate-based metal organic framework.
► The metal organic framework with unprecedented (3,9)-connected gfy topology.
► Representing the first Cu–I cluster based MOF with the gfy topology and 1D hexagonal nano-channels.
Journal: Inorganic Chemistry Communications - Volume 17, March 2012, Pages 169–172