Zinc and thiocyanate-mediated oxazolidine ring formation in a trinuclear zinc(II) complex: Synthesis, structure, and properties

A novel trinuclear zinc(II) complex, [Zn3L2(NCS)2], where L is the deprotonated form of 2-(3-(2-(2-hydroxy-3-methoxybenzylideneamino)ethyl)oxazolidin-2-yl)-6-methoxyphenol (H2L), has been unexpectedly prepared from the reaction of Schiff base ligand 2-((2-(2-hydroxyethylamino)ethylimino)methyl)-6-methoxyphenol (HL′) with 3-methoxysalicylaldehyde, ammonium thiocyanate, and zinc nitrate in methanol. The complex has been characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction studies. It is interesting that the Schiff base ligand HL′ used to prepare the complex was transferred to a novel ligand H2L, bearing newly formed oxazolidine ring. Zinc ion and thiocyanate anion may be the essential factors for the cyclorization. Thermal stability and fluorescent property of the complex were also studied.

A novel trinuclear zinc(II) complex has been unexpectedly prepared from the reaction of Schiff base ligand 2-((2-(2-hydroxyethylamino)ethylimino)methyl)-6-methoxyphenol with 3-methoxysalicylaldehyde, ammonium thiocyanate, and zinc nitrate in methanol. Zinc ion and thiocyanate anions may be the essential factors for the cyclorization between the ligands.Figure optionsDownload as PowerPoint slideHighlights
► A new trinuclear zinc complex with Schiff base ligands was prepared.
► The complex has been characterized by single crystal X-ray diffraction.
► Zinc ion and thiocyanate anions may be the essential factors for the cyclorization.
► The probable mechanism was presented.
► Thermal stability and fluorescence of the complex were studied.