کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1302283 974682 2010 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Three new d10 coordination polymers based on 2-(2-pyridyl)benzimidazole ligand: Synthesis, structures and properties
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Three new d10 coordination polymers based on 2-(2-pyridyl)benzimidazole ligand: Synthesis, structures and properties
چکیده انگلیسی

Three coordination polymers containing 2-(2-pyridyl)benzimidazole (PyHBIm) ligand, namely {[Zn3(PyBIm)3(PyHBIm)2(tma)(H2O)]
• H2O}n (1), [Zn(PyHBIm)(oba)]n (2), [Cd(PyHBIm)(oba)]n (3), (tma = trimesate, oba = 4,4′-oxybis-(benzoate)), have been prepared through hydrothermal reaction. Compound 1 exhibits one-dimensional (1D) helical structure. However, compounds 2 and 3 display 1D meso-helical structure. These 1D structures are further assembled into three-dimensional (3D) networks through aromatic π–π stacking interactions and hydrogen bonding interactions. Moreover they all exhibit strong photoluminescence at room temperature and may be good candidates for potential luminescence materials.

Graphical AbstractThree new coordination polymers containing 2-(2-pyridyl)benzimidazole (PyHBIm) ligand, namely {[Zn3(PyBIm)3(PyHBIm)2(tma)(H2O)]
• H2O}n (1), [Zn(PyHBIm)(oba)]n (2), [Cd(PyHBIm)(oba)]n (3), (tma = trimesate, oba = 4,4′-oxybis(benzoate)), have been prepared through hydrothermal reaction. They exhibit two different kinds of 1D helical structures. Compound 1 exhibits 1D helical structure. However, compounds 2 and 3 display 1D meso-helical structure.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 13, Issue 11, November 2010, Pages 1332–1336
نویسندگان
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