Two Pb(II) coordination polymers constructed from dicarboxamido-(2-pyridyl)-pyridine by varying ratios of mixed solvents

Through varying the volume ratio of mixed solvent, we obtained two distinct polymers {[Pb6(2,6-pda)6] · H2O}n (1) (2,6-pda = 2,6-pyridyldicarboxylate) and [Pb(mpcp)(OAc)]n (2) (mpcp = methyl-6-(pyridin-2-ylcarbamoyl)picolinate) by reaction of Pb(OAc)2 · 3H2O and 2,6-dicarboxamido-(2-pyridyl)-pyridine (H2dcapp) decomposed through lead-induced hydrolysis. Photoluminescence investigations reveal that both polymers display enhanced emissions in contrast to the free ligand, respectively.

By varying the ratio of DMF/MeOH solvent, we obtained a 3D microporous-structural polymer {[Pb6(2,6-pda)6] · H2O}n (1) (2,6-pda = 2,6-pyridyldicarboxylate) and a 1D chain polymer [Pb(mpcp)(OAc)]n (2) (mpcp = methyl-6-(pyridin-2-ylcarbamoyl)picolinate) via the reaction of Pb(OAc)2 · 3H2O and 2,6-dicarboxamido-(2-pyridyl)-pyridine (H2dcapp), which decomposes through lead-induced hydrolysis.Figure optionsDownload as PowerPoint slide