کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1302374 974687 2008 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The synthesis and characterization of new organosoluble long chain-substituted metal-free and metallophthalocyanines by microwave irradiation
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
The synthesis and characterization of new organosoluble long chain-substituted metal-free and metallophthalocyanines by microwave irradiation
چکیده انگلیسی
The long chain-substitued phthalonitrile (3) was synthesized by nucleophilic displacement of nitro group in 4-nitrophthalonitrile with N,N-bis[2-(2-hyroxyethoxy)ethyl]-4-methylbenzenesulfonamide (1). The novel metal-free phthalocyanine (4) and metallophtalocyanines (5-8) have been synthesized by cyclotetramerization reaction of phthalonitrile derivative (3). Long chain-substitued Pcs showed the enhanced solubility in organic solvents. The new compounds were characterized by a combination of IR, 1H NMR, 13C NMR, UV-vis, elemental analysis and MS spectral data.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 11, Issue 12, December 2008, Pages 1448-1451
نویسندگان
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