کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1302457 | 974693 | 2011 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and characterization of new metal-free and metallophthalocyanines containing macrobicyclic moieties Synthesis and characterization of new metal-free and metallophthalocyanines containing macrobicyclic moieties](/preview/png/1302457.png)
The synthesis and characterization of novel metal-free and cobalt phthalocyanine, peripherally symmetrically derived from 2,3,6,7,10,11,13,14-octahydro-5H,9H-4,12-(propanothiopropano)-1,8,15,23,4,12-benzotetrathiodiazacycloheptadecane-17,18-dicarbonitrile (4) which was prepared by the reaction of 1,9-diaza-5,13-dithiocyclohexadecane (3) and 1,2-bis(2-iodoethylmercapto)-4,5-dicyanobenzene (2) was carried out. The novel compounds were characterized by using elemental analysis, 1H, 13C NMR, IR, UV–vis and MS techniques.
New metal-free phthalocyanine (H2Pc) and cobalt phthalocyanine (CoPc) containing four peripheral mixed donor macrobicyclic moieties has been prepared by a cyclotetramerisation reaction of macrobicyclic dinitrile (4).Figure optionsDownload as PowerPoint slideHighlights
► Different synthetic approaches concerning (2) was investigated and the novel route was found.
► The synthesis of compound (4) containing N2S4 macrobicyclic moiety has been accomplished.
► Novel phthalocyanines bearing peripheral N2S4 macrobicyclic moieties were synthesized.
Journal: Inorganic Chemistry Communications - Volume 14, Issue 12, December 2011, Pages 1880–1883