کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1302533 | 974698 | 2011 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Unique example of a trigonal dodecahedral Na+ in a compartmental Schiff base N,N′-(1,2-Phenylene)-bis(3-methoxysalicylideneimine) Unique example of a trigonal dodecahedral Na+ in a compartmental Schiff base N,N′-(1,2-Phenylene)-bis(3-methoxysalicylideneimine)](/preview/png/1302533.png)
A unique heteronuclear Schiff base compound, [(NiL)Na(NiL)]ClO4 (1), derived from the compartmental Schiff base ligand N,N′-(1,2-Phenylene)-bis(3-methoxysalicylideneimine) (H2L) has been prepared and its molecular structure has been elucidated on the basis of X-ray crystallography. The compound contains an octa-coordinated Na+ in trigonal dodecahedral geometry and two terminal square planar Ni(II).
A unique heteronuclear Schiff base compound, [(NiL)Na(NiL)]ClO4 with two terminal square planar Ni(II) and trigonal dodecahedral Na+, derived from the Schiff base compartmental ligand N,N′-(1,2-Phenylene)-bis(3-methoxysalicylideneimine) (H2L) has been prepared and its molecular structure has been elucidated on the basis of by X-ray crystallography.Figure optionsDownload as PowerPoint slideResearch highlights
► Unique heteronuclear Schiff base compound with a compartmental Schiff base ligand.
► Structure elucidated on the basis of X-ray crystallography.
► Octa-coordinated Na+ in trigonal dodecahedral geometry.
► Square planar Ni(II).
Journal: Inorganic Chemistry Communications - Volume 14, Issue 9, September 2011, Pages 1337–1340