کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1302664 | 974707 | 2007 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis, structure, and magnetic properties of a novel mixed-bridged heterometal tetranuclear complex [Mn2Ni2(MeOSalen)2(μ1,1-N3)2(N3)2] Synthesis, structure, and magnetic properties of a novel mixed-bridged heterometal tetranuclear complex [Mn2Ni2(MeOSalen)2(μ1,1-N3)2(N3)2]](/preview/png/1302664.png)
The first heterometal tetranuclear complex with alternating azido and phenoxo bridges, [Mn2Ni2(MeOSalen)2(μ1,1-N3)2(N3)2] (MeOSalenH2 = bis(3-methoxy)salicylideneimine), was synthesized and structurally characterized by X-ray crystallography and spectroscopic methods. Magnetic studies suggest there is a ferromagnetic interaction between the μ1,1-azido-bridged Mn(II) ions with J = +2.11 cm−1, while the Ni(II) ions are diamagnetic in the tetranuclear system.
The first heterometal tetranuclear complex with alternating azido and phenoxo bridges, [Mn2Ni2(MeOSalen)2(μ1,1-N3)2(N3)2] was synthesized and characterized. There is a ferromagnetic interaction between the azido- bridged Mn(II) ions while the Ni(II) ions are diamagnetic.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 10, Issue 4, April 2007, Pages 397–400