کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1302692 | 974707 | 2007 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
First example of pyrrole-2-carbaldehyde thiosemicarbazone as tridentate dianion in [Pd(η3-N4,N3,S-ptsc)(PPh3)] complex
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: First example of pyrrole-2-carbaldehyde thiosemicarbazone as tridentate dianion in [Pd(η3-N4,N3,S-ptsc)(PPh3)] complex First example of pyrrole-2-carbaldehyde thiosemicarbazone as tridentate dianion in [Pd(η3-N4,N3,S-ptsc)(PPh3)] complex](/preview/png/1302692.png)
چکیده انگلیسی
Reaction of pyrrole-2-carbaldehyde thiosemicarbazone (H2ptsc) with PdCl2(PPh3)2 in 1:1 mol ratio in presence of Et3N leads to complete dechlorination to generate square planar complex, [Pd(η3-N4,N3,S-ptsc)(PPh3)] (1), existing as three independent molecules in the same unit cell, and H2ptsc behaves in an unusual dinegative tridentate mode. Salicylaldehyde thiosemicarbazone (H2stsc) formed similar compound, [Pd(η3-O,N3,S-stsc)(PPh3)] (3).
Pyrrole-2-carbaldehyde thiosemicarbazone (H2ptsc) with PdCl2(PPh3)2 forms a square planar complex, [Pd(η3- N4,N3,S-ptsc)(PPh3)] (1), existing as three independent molecules in the same unit cell, and H2ptsc behaves in an unusual dinegative tridentate mode.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 10, Issue 4, April 2007, Pages 506–509
Journal: Inorganic Chemistry Communications - Volume 10, Issue 4, April 2007, Pages 506–509
نویسندگان
Tarlok S. Lobana, Gagandeep Bawa, Alfonso Castineiras, Ray J. Butcher,