کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1302791 | 974711 | 2006 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis, characterization and conducting properties of complex salts and heterobimetallic coordination polymers of the cyanodithioimidocarbonato ligand Synthesis, characterization and conducting properties of complex salts and heterobimetallic coordination polymers of the cyanodithioimidocarbonato ligand](/preview/png/1302791.png)
The complex salts (NPr4n)2[M′(cdc)2] and the heterobimetallic coordination polymers [MM′(cdc)2] [M = Zn(II), Cd(II), Hg(II), 2Ag(I) or Pb(II); M′ = Ni(II) or Cu(II); cdc2− = cyanodithioimidocarbonate] have been prepared and characterized by elemental analysis, solution and solid state conductivity, magnetic susceptibility, IR, 1H and 13C NMR, UV–Vis, EPR and FAB-mass spectrometry. All of the compounds exhibited semiconducting behaviour.
The reaction of K2[M′(cdc)2]with NPr4nI and metal salts MX2 have afforded complex salts (NPr4n)2[M′(cdc)2] and heterobimetallic coordination polymers [MM′(cdc)2] [M′ = Ni(II) or Cu(II); M = Zn(II), Cd(II), Hg(II), 2Ag(I) or Pb(II)] which have been investigated using spectroscopic, magnetic and solid state electrical concductivity technique.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 9, Issue 10, October 2006, Pages 1058–1062