کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1302816 | 974713 | 2011 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: A novel inorganic–organic hybrid 1D chain built by double banana-shaped tungstoarsenates {Co(Hen)[Co6As3W24O94(H2O)2]}228− A novel inorganic–organic hybrid 1D chain built by double banana-shaped tungstoarsenates {Co(Hen)[Co6As3W24O94(H2O)2]}228−](/preview/png/1302816.png)
A novel inorganic–organic hybrid 1D chain tungstoarsenate (H2en)4H20{Co(Hen) [Co6As3W24O94(H2O)2]}2·15H2O (en = ethylenediamine) (1) has been hydrothermally synthesized and characterized by elemental analysis, IR spectrum and single-crystal X-ray diffraction. 1 contains a double banana-shaped tungstoarsenate anion {Co(Hen)[Co6As3W24O94(H2O)2]}228−, which is established by two banana-shaped {Co(Hen)[Co6As3W24O94(H2O)2]}14− subunits linked together by a W–O–Co bridge. More importantly, adjacent double banana-shaped polyoxoanions {Co(Hen)[Co6As3W24O94(H2O)2]}228− are interconnected by W–O–Co linkers leading to the 1D chain architecture, to our knowledge, which represents the first inorganic–organic hybrid 1D chain constructed from double banana-shaped polyoxoanions. Magnetic measurements indicate that there are the antiferromagnetic interactions within the cobalt centers.
The first inorganic–organic hybrid 1D chain tungstoarsenate (H2en)4H20{Co(Hen)[Co6As3W24O94(H2O)2]}2·15H2O built by double banana-shaped units {Co(Hen)[Co6As3W24O94(H2O)2]}228− has been hydrothermally synthesized and structurally characterized.Figure optionsDownload as PowerPoint slideResearch Highlights
► A new inorganic–organic hybrid tungstoarsenate contains double banana-shaped anions.
► The hybrid represents the first 1D chain based double banana-shaped polyoxoanions.
► The [Co(Hen)]3+ cation displays an uncommon end-on coordination motif in POM field.
► Antiferromagnetic exchange interactions exist in trinuclear CoII clusters.
Journal: Inorganic Chemistry Communications - Volume 14, Issue 2, February 2011, Pages 415–418