کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1302831 | 974715 | 2006 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
An unprecedented example of polyoxotungstates: Synthesis and characterization of an octatungstate complex [W8O19L3(acac)4] (L = −O(CH2)3S(CH2)3O−)
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: An unprecedented example of polyoxotungstates: Synthesis and characterization of an octatungstate complex [W8O19L3(acac)4] (L = −O(CH2)3S(CH2)3O−) An unprecedented example of polyoxotungstates: Synthesis and characterization of an octatungstate complex [W8O19L3(acac)4] (L = −O(CH2)3S(CH2)3O−)](/preview/png/1302831.png)
چکیده انگلیسی
A new polyoxotungstate cluster [W8O19L3(acac)4] (L = −O(CH2)3S(CH2)3O −; acac = acetylacetonate), was synthesized and characterized by single-crystal X-ray diffraction. The structure of the octatungstate cluster exhibits a novel unprecedented polyoxotungstate mode.
The reaction of WO2(acac)2 with bis(3-hydroxypropyl)sulfide yields a novel octatungstate-supported molecular cluster [W8O19L3(acac)4] (L = −O (CH2)3S(CH2)3O−; acac = acetylacetonate), which exhibits an unprecedented polyoxotungstate mode. Synthesis, formation of the cluster and its structure are discussed.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 9, Issue 8, August 2006, Pages 777–781
Journal: Inorganic Chemistry Communications - Volume 9, Issue 8, August 2006, Pages 777–781
نویسندگان
Xiaoli Ma, Zhi Yang, Carola Schulzke, Hans-Georg Schmidt, Mathias Noltemeyer,