کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1302910 | 974720 | 2006 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: New tin(II) and tin(IV) amidophenolate complexes New tin(II) and tin(IV) amidophenolate complexes](/preview/png/1302910.png)
Treatment of tin amalgam with 4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzoquinone (imQ) in THF results in formation of bis-(4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-amidophenolato)tin(IV) tetrahydrofuranate (1). The exchange reaction of imQ dilithium derivative with tin dichloride dioxanate in THF solution produces bis-[(4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-amidophenolato)tin(II)] (2). Stannylene (2) reacts with imQ in THF to give 1. Structures of 1 and 2 were determined by X-ray analysis.
Treatment of tin amalgam with 4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzoquinone (imQ) in THF results in formation of bis-(4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-amidophenolato)tin(IV) tetrahydrofuranate (1). The exchange reaction of imQ dilithium derivative with tin dichloride dioxanate in THF solution produces bis-[(4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-amidophenolato)tin(II)] (2). Stannylene (2) reacts with imQ in THF to give 1. Structures of 1 and 2 were determined by X-ray analysis.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 9, Issue 6, June 2006, Pages 612–615