کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1303127 | 974743 | 2009 | 4 صفحه PDF | دانلود رایگان |
The first example of a hexacoordinate phosphorus compound [S{6-t-Bu-4-Me-C6H2O}2]2P+(Cl−·C3H4N2) with two S→P bonds is reported. This compound can be construed as an oxophosphonium salt with double intramolecular coordination by sulfur atoms. X-ray structure reveals a facial arrangement of the ligands with two coordinating sulfur atoms cis to each other. The S→P distance of 2.334 (1) Å is one among very short coordinate bond distances between sulfur and phosphorus.
Synthesis and X-ray structure of the first example of a hexacoordinate phosphorus compound [S{6-t-Bu-4-Me-C6H2O}2]2P+[Cl−·(C3H4N2)] with two S→P bonds is reported. This novel compound can be construed as an oxophosphonium salt with double intramolecular coordination by sulfur atoms.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 12, Issue 6, June 2009, Pages 544–547