کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1303203 | 1498923 | 2016 | 5 صفحه PDF | دانلود رایگان |
• Crystals of title compound are obtained via an aqueous solution-evaporation method.
• Dielectric transition and relaxation occur between 120 and 180 K.
• One of the two HIm cations undergoes a static-dynamic disorder transition.
Organic-inorganic hybrid compound (HIm)6[(CdCl4)(CdCl6)] (Im = imidazole) shows a striking dielectric transition and relaxation between 120 and 180 K. Variable-temperature single crystal structure analysis and dielectric measurement reveal one half of the HIm cations in the crystal undergoes a transition between the static and dynamic disorders.
Motional changes of one half of the HIm cations in the imidazolium-based crystal (HIm)6[(CdCl4)(CdCl6)] shows dielectric transition and relaxation behaviors between 120 and 180 K.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 67, May 2016, Pages 35–39