کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1303248 | 974753 | 2008 | 4 صفحه PDF | دانلود رایگان |
Complementary amide H-bond interactions of chiral C2-symmetric bis(amide) ligand BINDC, (N,N′-bis(isonicotinoyl)-(1R,2R)-diaminocyclohexane) in Zn(BINDC)Cl2 (1), Zn(BINDC)Br2 (2) and Ag(BINDC)NO3 (3) metal-organic frameworks (MOFs) lead to the formation of hierarchical network structures. The strong H-bond interactions coupled with coordinate bond leads to enhanced thermal stability to the materials. Moreover, the MOFs show solid state second harmonic generation (SHG) and good optical transparency in the visible range.
Complementary amide H-bond interactions of chiral C2-symmetric bis(amide) ligand BINDC, (N,N′-bis(isonicotinoyl)-(1R,2R)-diaminocyclohexane) in Zn(BINDC)Cl2 (1), Zn(BINDC)Br2 (2) and Ag(BINDC)NO3 (3) metal-organic frameworks (MOFs) lead to the formation of hierarchical network structures. The MOFs show solid state second harmonic generation (SHG) and good optical transparency in the visible range.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 11, Issue 7, July 2008, Pages 791–794