Sulfur bridging by acetophenone thiosemicarbazone in [Ag(μ-dppm)2(μ-SR)Ag(ONO2)](NO3) dimer with a new {Ag2(μ-P,P)2(μ-SR)} core

Acetophenone thiosemicarbazone (Haptsc) with silver(I) nitrate and Ph2P–CH2–PPh2 (dppm) has formed a first example of triply hetero-bridged [Ag(μ-P,P-dppm)2(μ-S-Haptsc)Ag(ONO2)]NO3 dimer with a short Ag⋯Ag contact of 2.9939(7) Å.

Acetophenone thiosemicarbazone bridging of {Ag(μ-P,P)2Ag} core has formed an unusual hetero-bridged dimer, [Ag(μ-P,P-dppm)2(μ-S-Haptsc)Ag(ONO2)]NO31, with a short Ag⋯Ag contact.Figure optionsDownload as PowerPoint slide