کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1303317 | 974758 | 2007 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis, crystal structure and bioactivity of a novel linear trinuclear nickel(II) complex Synthesis, crystal structure and bioactivity of a novel linear trinuclear nickel(II) complex](/preview/png/1303317.png)
A novel linear trinuclear nickel(II) complex, [Ni3(H2O)2(DMA)2(acbshz)2]·2DMF (DMA = dimethylamine; acbshz = N-acryloyl-5-bromosalicylhydrazide), has been prepared by self-assembly approach. The three nickel atoms arrange in a strictly linear structure, adjacent molecules are linked by intermolecular H bonds to form a 2D infinite wave-like structure. Antibacterial screening data indicate the formation of the trinuclear complex reduced the antimicrobial activity of the ligand.
The three nickel ions in this novel trinuclear complex arrange in a strictly linear structure, and exhibit alternating square-planar and octahedral coordination environments. It shows a wave-like 2D structure formed by intermolecular H bonds.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 10, Issue 11, November 2007, Pages 1351–1354