Two Mn(II)-Au(I) supramolecular assemblies bonded by coordination, aurophilicity and hydrogen-bonding, π-π interactions and their magnetic properties

Two Mn(II)-Au(I) supramolecular assemblies have been synthesized and structurally characterized by single crystal X-ray diffraction. The interplay of aurophilicity, coordination, hydrogen-bonding and π-π interactions in 1 and 2 result in three-dimensional network.