کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1303403 | 974767 | 2007 | 4 صفحه PDF | دانلود رایگان |
A new cobalt(III) complex salt, [cis-Co(en)2(H2O)Cl](C6H5SO3)2 · H2O] (I) has been synthesized and characterized by single crystal X-ray structure determination and NMR spectroscopy. This is a first report of the cobalt(III) cation in cis-configuration. The crystal lattice of the complex salt is stabilized by electrostatic forces of attraction and hydrogen bonding interactions.
A new cobalt(III) complex salt, [cis-Co(en)2(H2O)Cl](C6H5SO3)2, has been synthesized and characterized by single crystal X-ray structure determination. This is a first structural report of the cation [Co(en)2(H2O)Cl]2+ in cis-configuration. The cations and anions are associated in chains by strong NH⋯O hydrogen bonds. The crystal lattice is stabilized by extensive hydrogen bonding besides coulombic forces of attraction.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 10, Issue 2, February 2007, Pages 139–142