کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1303630 | 974777 | 2006 | 4 صفحه PDF | دانلود رایگان |
A new photoluminescent copper(I) cyanide polymer [(CuCN)4(bix)]n (bix = 1,4-bis(imidazole-l-ylmethyl)benzene) has been hydrothermally synthesized and structurally characterized. The structure of this complex features a vase-shaped 3D network of {Cu(CN)} substructure constructed from the puckered layers containing large 34-membered Cu–CN–Cu rings. The present compound was characterized using IR, Elemental analysis and X-ray single-crystal analysis. The photoluminescent property of the title compound was also investigated.
The hydrothermal reaction of CuCN and bix (bix = 1,4-bis(imidazole-l-ylmethyl)benzene) in the presence of 4,5-imidazoledicarboxylic acid and HCl in water leads to formation of the pale yellow crystals. The structure of this complex features a vase-shaped 3D network of {Cu(CN)} substructure constructed from the puckered layers containing large 34-membered Cu–CN–Cu rings.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 9, Issue 7, July 2006, Pages 675–678