کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1303798 | 1498958 | 2013 | 4 صفحه PDF | دانلود رایگان |
• A novel supramolecular polymer with formula [Cu{(CH3)2SO}6]I4 has been synthesized.
• The cationic units are connected through self-assembly process with iodide anions.
• The linear and centrosymmetric polyiodide anion is a rare example of a tetraiodide.
The structure of the new complex with molecular formula [Cu{(CH3)2SO}6]I4, has been determined. The compound comprises discrete [Cu{(CH3)2SO}6]2 + units connected through a self-assembly process with a linear arrangement of polyiodide I2n + 22 −, driven by non-classical hydrogen bonds CH∙∙∙I. The polyiodide chain presents a neutral I2 molecule weakly coordinated with two iodide anions. The linear, uncoordinated, centrosymmetric polyiodide anion represents a rare example of a tetraiodide.
A novel supramolecular polymer has been synthesized. The compound comprises discrete [Cu{(CH3)2SO}6]2 + units connected through a self-assembly process with a linear arrangement of polyiodide I2n + 22 −, driven by non-classical hydrogen bonds CH∙∙∙I.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 32, June 2013, Pages 64–67