کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1303824 | 1498955 | 2013 | 4 صفحه PDF | دانلود رایگان |
• Novel dinuclear Co(III)–CN–Fe(III) compound was prepared and characterized.
• Magnetic analysis revealed significant zero-field splitting on Fe(III).
• Utilization of the compound as a potential building block is outlined.
X-ray structure and magnetic properties of a novel dinuclear heterobimetallic CoIII–CN–FeIII compound of the composition [{Co(3EtO-L5)}(μ-CN){Fe(L4)(Cl)}] (2) is reported. Adjacent complex molecules are connected through intermolecular N―H⋅⋅⋅Cl hydrogen bonds into 1D supramolecular chains. Such a compound can be considered as a potential building block for the preparation of Prussian blue analogues of high nuclearity showing interesting magnetic properties.
X-ray structure and magnetic properties of a dinuclear heterobimetallic CoIII–CN–FeIII compound of the composition [{Co(3EtO-L5)}(μ-CN){Fe(L4)(Cl)}] (2) is reported.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 35, September 2013, Pages 50–53