کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1303824 1498955 2013 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Cobalt(III) Schiff-base cyanido complex usable as a ligand in preparation of heterobimetallic Co(III)–Fe(III) building blocks
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Cobalt(III) Schiff-base cyanido complex usable as a ligand in preparation of heterobimetallic Co(III)–Fe(III) building blocks
چکیده انگلیسی


• Novel dinuclear Co(III)–CN–Fe(III) compound was prepared and characterized.
• Magnetic analysis revealed significant zero-field splitting on Fe(III).
• Utilization of the compound as a potential building block is outlined.

X-ray structure and magnetic properties of a novel dinuclear heterobimetallic CoIII–CN–FeIII compound of the composition [{Co(3EtO-L5)}(μ-CN){Fe(L4)(Cl)}] (2) is reported. Adjacent complex molecules are connected through intermolecular N―H⋅⋅⋅Cl hydrogen bonds into 1D supramolecular chains. Such a compound can be considered as a potential building block for the preparation of Prussian blue analogues of high nuclearity showing interesting magnetic properties.

X-ray structure and magnetic properties of a dinuclear heterobimetallic CoIII–CN–FeIII compound of the composition [{Co(3EtO-L5)}(μ-CN){Fe(L4)(Cl)}] (2) is reported.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 35, September 2013, Pages 50–53
نویسندگان
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