کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1303907 | 1498965 | 2012 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
One-pot synthesis of two high-connected metal–organic frameworks constructed from [Cu2Na2I2]2 + and [Cu6I4]2 + clusters and tetrazolate ligand formed in-situ
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: One-pot synthesis of two high-connected metal–organic frameworks constructed from [Cu2Na2I2]2 + and [Cu6I4]2 + clusters and tetrazolate ligand formed in-situ One-pot synthesis of two high-connected metal–organic frameworks constructed from [Cu2Na2I2]2 + and [Cu6I4]2 + clusters and tetrazolate ligand formed in-situ](/preview/png/1303907.png)
چکیده انگلیسی
By in-situ formation of the tetrazolate ligand, 5-(3-pyridyl)tetrazole (L′), two three-dimensional metal–organic frameworks [CuI(L′)Na]n (1) and [Cu3I2L′]n (2), have been one-pot synthesized and constructed by the heterometallic cation cluster (Cu2I2Na2)2 + and (Cu6I4)2 + cluster as ten connected nodes, respectively.
Presented here are two high-connected metal–organic frameworks based on cationic CuI clusters.Figure optionsDownload as PowerPoint slideHighlights
► The construction of two new MOFs with high-connected nodes.
► The observation of a (5,10)-connected fit topology network and new [Cu2I2Na2]2 + cation cluster.
► The observation of an unprecedented (3,10)-connected (43)2(418·624·83) net and [Cu6I4]2 + cation cluster.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 25, November 2012, Pages 21–25
Journal: Inorganic Chemistry Communications - Volume 25, November 2012, Pages 21–25
نویسندگان
Fei Wang, Xiao-Yuan Wu, Rongmin Yu, Can-Zhong Lu,