کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1303951 1498968 2012 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis, crystal structures and competitive binding property of a family of functionalized calix[4]arene ionophores
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis, crystal structures and competitive binding property of a family of functionalized calix[4]arene ionophores
چکیده انگلیسی

A family of calix-crown hybrid molecules incorporating crown-4, crown-5 and crown-6 moieties as ionophore has been synthesized to evaluate their competitive complexing and extracting ability towards different alkali and alkaline earth metal ions. Selectivity of these ionophores towards Li+, Na+, K+, Ca2+, Mg2+ and Sr2+ has been evaluated with aqueous solution containing equimolar mixture of these ions. The concentration of metal ion in the extract (organic phase) has been estimated by ion chromatographic assay. Two of the ionophores show strong complexation with Na+ and K+, whereas the third ionophore exhibits no complexation with any metal ions used in this study. Association constants (Ka) for the binding of Na+ and K+ with two of these ionophores have been determined spectrophotometrically. Molecular structures of the Na+ and K+ complexes of these ionophores have been established by single crystal X-ray study. 1H NMR study of the ionophores and their complexes has also been carried out to investigate conformational behavior of the ionophores and their metal complexes in solution. Results have been discussed in light of various factors contribute to determine ion-selectivity.

Competitive complexing ability of a number of calix-crown hybrid molecules has been studied using a series of alkali and alkaline earth metal ions in aqueous media; selectivity and binding constants have evaluated and the molecular structures of the complexes formed have been determined by single crystal X-ray study.Figure optionsDownload as PowerPoint slideHighlights
► A family of calix-crown hybrid molecules as chemo sensor has been synthesized.
► Competitive complexing ability of these ionophores has been evaluated.
► Selectivity has been determined by estimation of metal ions in the extract.
► X-ray structures of the complexes formed have been determined.
► It reveals that the size-matching factor plays predominant role in ion-selectivity.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 22, August 2012, Pages 85–89
نویسندگان
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