Assembly of two new Mn(II) coordination polymers based on 5-aminoisophthalate: Structural diversity and properties

Two new Mn(II) coordination polymers, namely, [Mn(Haip)2(H2O)2] (1), and [Mn2(aip)2(bpy)]·3H2O (2) were obtained under hydrothermal conditions (aip = 5-aminoisophthalate; bpy = 2, 2′-bipyridine). Compound 1 features a 1D loop-like chain structure, and complex 2 possesses an interesting (3, 5)-connected 2-nodal 3D architecture with the Schläfli symbol of (4.62)(4.67.82), which is constructed from helical chains. Coordination modes of H2aip molecules and coligands have significant effect on the structures of the resulting complexes. Moreover, variable-temperature magnetic susceptibility measurement of complex 2 exhibits antiferromagnetic interactions between nearest Mn(II) ions with J = − 0.88(5) cm− 1 and g = 2.04(3).

Two complexes possess a 1D chain and a (3, 5)-connected 2-nodal 3D architecture, respectively. Variable-temperature magnetic susceptibility measurement of compound 2 shows antiferromagnetic interactions between nearest Mn(II) ions.Figure optionsDownload as PowerPoint slideHighlights
► Two complexes with different topologies are obtained via hydrothermal reactions.
► Complex 2 was constructed by connection of dinuclear Mn(II) building blocks.
► Coligand and coordination modes of aip affected on structures of two complexes.
► Complex 2 exhibits antiferromagnetic interactions between nearest Mn(II) ions.