کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1304039 | 1498975 | 2012 | 4 صفحه PDF | دانلود رایگان |
Herein, a special water cluster was observed in a metal-organic framework, namely [Zn(μ-(H2O)2)(L)(BDC)]·5H2O (1, L = 2-(pyridine-4-yl)-1H-benzo[d]imidazole, H2BDC = terephthalic acid). In this ice-like water cluster, tetramer water clusters are combined together by sharing one corner to give rise to the T4(1) water structure, while the pentamer water clusters are located on two sides of this T4(1) water chain by sharing two edges with two tetramer water clusters, thus resulting in the overall T4(1)4(2)5(2) water topology.
A special water cluster was observed, where tetramer water clusters are combined together to create the T4(1) water structure, while the pentamer water clusters are located on two sides of it, thus resulting in the overall T4(1)4(2)5(2) water topology.Figure optionsDownload as PowerPoint slideHighlights
► Presented here is a highly rare water structure.
► Both tetramer and pentamer water are contained.
► It is defined as T4(1)4(2)5(2) water topology.
Journal: Inorganic Chemistry Communications - Volume 15, January 2012, Pages 252–255