کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1304340 | 974819 | 2010 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, structure and properties of a new copper (II) complex, [Cu2(4,4′-bpy)5(H2O)4](ClO4)4(4,4′-bpy)(DMF)2(H2O)2
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A new copper (II) complex with formula [Cu2(4,4′-bpy)5(H2O)4](ClO4)4(4,4′-bpy)(DMF)2(H2O)2 has been synthesized by reaction of 4,4′-bpyridine (4,4′-bpy) with Cu(ClO4)2. While strong hydrogen bonds play central roles in the formation of the 3D structure, the combined influence of the weak interactions such as C–H⋯O bonds, anion⋯π and C–H⋯π interactions are also evident in the structure. The preliminary investigation on the thermal property of the complex is presented.
Various solvent and anions (H2O, ClO4−, DMF, 4,4′-bpy) were encapsulates inside the channels (channel a, b, c and d) of the 3D networks which act as a host to stabilize the structure.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 13, Issue 6, June 2010, Pages 720–723
Journal: Inorganic Chemistry Communications - Volume 13, Issue 6, June 2010, Pages 720–723
نویسندگان
Feilong Hu, Xianhong Yin, Yan Mi, Wanshu Li, Xinping Tang, Zhen Ma,