کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1304351 974819 2010 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Three-dimensional microporous metal–organic framework constructed from Cadmium(II) ion with terephthalate and in-situ generated amino-tetrazole mixed-ligands
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Three-dimensional microporous metal–organic framework constructed from Cadmium(II) ion with terephthalate and in-situ generated amino-tetrazole mixed-ligands
چکیده انگلیسی

A new coordination polymer, [Cd4(atz)6(PTA)]n has been firstly synthesized by employing mixed-ligand of terephthalic acid (PTA) with the in-situ generated ligand of 5-amino-tetrazolate (atz−). Compound 1 represents a 3D microporous framework constructed from Cd-tetrazolate subunits and the subunits are bridged by PTA and atz ligands. When the subunit was collided into node, compound 1 possesses an unprecedented 3, 9-connected topological network. Furthermore, the investigations of thermal stability and luminescent property of complex 1 indicate that compound 1 may be an excellent candidate for potential blue-light emitting material.

A new coordination polymer, [Cd4(atz)6(PTA)]n has been firstly synthesized by employing mixed-ligand synthetic approach. Compound 1 presents a 3D microporous framework with an unprecedented 3, 9-connected topological network.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 13, Issue 6, June 2010, Pages 762–765
نویسندگان
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