کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1304351 | 974819 | 2010 | 4 صفحه PDF | دانلود رایگان |

A new coordination polymer, [Cd4(atz)6(PTA)]n has been firstly synthesized by employing mixed-ligand of terephthalic acid (PTA) with the in-situ generated ligand of 5-amino-tetrazolate (atz−). Compound 1 represents a 3D microporous framework constructed from Cd-tetrazolate subunits and the subunits are bridged by PTA and atz ligands. When the subunit was collided into node, compound 1 possesses an unprecedented 3, 9-connected topological network. Furthermore, the investigations of thermal stability and luminescent property of complex 1 indicate that compound 1 may be an excellent candidate for potential blue-light emitting material.
A new coordination polymer, [Cd4(atz)6(PTA)]n has been firstly synthesized by employing mixed-ligand synthetic approach. Compound 1 presents a 3D microporous framework with an unprecedented 3, 9-connected topological network.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 13, Issue 6, June 2010, Pages 762–765