کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1304499 974830 2010 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Bis(3,5-dimethylpyrazol-1-yl)alkanones and their reactivity with [PdCl2(NCMe)2]: Isolation of bis(3,5-dimethylpyrazol-1-yl)propan-1-one palladium(II) chloride and C–H activation of propanone linker
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Bis(3,5-dimethylpyrazol-1-yl)alkanones and their reactivity with [PdCl2(NCMe)2]: Isolation of bis(3,5-dimethylpyrazol-1-yl)propan-1-one palladium(II) chloride and C–H activation of propanone linker
چکیده انگلیسی

Four new bis(3,5-dimethylpyrazol-1-yl)alkanones were prepared by the reaction of the respective alkanoyl chloride with 3,5-dimethylpyrazole: L1 from chloropropionyl chloride, L2 from 4-chlorobutyryl chloride, L3 from oxalyl chloride and L4 from adipoyl dichloride; all in moderate yields. Of the four compounds only L1 successfully reacts with [PdCl2(NCMe)2] to yield [PdCl2(L1)] in 41% yield, which on heating in toluene leads to C–H activation to produce [PdCl(L1′)], where L1′ is deprotonated L1, in very low yield.

Bis(3,5-dimethylpyrazol-1-ylpropan-1-one forms palladium dichloride complex, which readily undergoes C–H activation to from an N^C^N pincer palladium complex, and thus demonstrates the potential of this pyrazolyl compound as a tridentate ligand.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 13, Issue 1, January 2010, Pages 123–126
نویسندگان
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