Synthesis, X-ray structures, and photoluminescence of heterometal trinuclear Hg(II)–Pt(I) and tetranuclear Hg(II)–Pd(I) complexes

A heterometallic trinuclear complex with monovalent platinum consisting of a [Pt2Hg] cluster bridged by two μ3-Cl atoms and another tetranuclear complex with monovalent palladium owning the structural core of open cubane-like [Hg2Pd2Cl2I2] framework were synthesized by self-assembly reactions.

A heterometallic trinuclear complex with monovalent platinum consisting of a [Pt2Hg] cluster bridged by two μ3-Cl atoms and another tetranuclear complex with monovalent palladium owning the structural core of open cubane-like [Hg2Pd2Cl2I2] framework was synthesized by self-assembly reactions.Figure optionsDownload as PowerPoint slide