کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1304605 974839 2008 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A novel hexanuclear iron(III) complex containing three-coordination symmetries with two bridging μ-alkoxo groups, two μ3-oxo and four μ-catecholato bridges
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
A novel hexanuclear iron(III) complex containing three-coordination symmetries with two bridging μ-alkoxo groups, two μ3-oxo and four μ-catecholato bridges
چکیده انگلیسی

The reaction of stoichiometric amount of FeCl3, Schiff-base ligand, NaBPh4 in CH3CN and 3,5-DTBC in CH3OH under O2 did produce a new μ-oxo-bridged hexanuclear iron(III) cluster [Fe6(L)2(μ3-O)2(μ-3,5-DTBC)4(μ-CH3O)2(Cl)2] (BPh4)2 · 2H2O (1) (L = N,N-diethylenetriamino-bis(imidazolaldiminato) with a spin ground state of S = 5.

The reaction of stoichiometric amount of FeCl3, Schiff-base ligand, NaBPh4 in CH3CN and 3,5-DTBC in CH3OH under O2 did produce a new μ-oxo-bridged hexanuclear iron(III) cluster with a spin ground state of S = 5.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 11, Issue 4, April 2008, Pages 388–391
نویسندگان
, , , ,