کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1304609 974839 2008 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Structural characterization of the first linearly arranged Ag3 complexes supported by naphthyridine-functionalized N-heterocyclic carbenes
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Structural characterization of the first linearly arranged Ag3 complexes supported by naphthyridine-functionalized N-heterocyclic carbenes
چکیده انگلیسی

Reactions of the imidazolium salts with Ag2O afforded trinuclear silver complexes [Ag3(L)2(CH3CN)](PF6)3 (L = 2,7-bis(alkylimidazolylidenyl)naphthyridine), which have been characterized by NMR spectroscopy and X-ray diffraction analysis. The complexes consist of linearly arranged Ag3 cores showing weak silver–silver interactions as evidenced by the short silver–silver contacts (3.10–3.24 Å). The complexes are intensely emissive in their solid states.

Two linearly arranged trinuclear silver complexes, [Ag3(L)2(CH3CN)](PF6)3 (L = 2,7-bis(alkylimidazolylidenyl)naphthyridine), have been characterized by NMR spectroscopy and X-ray diffraction analysis.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 11, Issue 4, April 2008, Pages 404–408
نویسندگان
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