کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1304715 | 974845 | 2008 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and structure of the first clathrochelate ligand with a cis-diimidazolyl donor fragment Synthesis and structure of the first clathrochelate ligand with a cis-diimidazolyl donor fragment](/preview/png/1304715.png)
The monoribbed-functionalized clathrochelate with two functionalizing imidazolyl substituents was synthesized by interaction of dichloroglyoximato-bis-α-benzyldioximate FeBd2(Cl2Gm)(BF)2 precursor with organomagnesium imidazole derivative. The N6-coordination polyhedron of the diimidazolyl iron(II) clathrochelate molecule has a distorted trigonal prismatic geometry with the distortion angle φ = 24.1° and the FeN distances approximately 1.91 Å.
The monoribbed-functionalized clathrochelate with two functionalizing imidazolyl substituents was synthesized by interaction of dichloroglyoximato-bis-α-benzyldioximate FeBd2(Cl2Gm)(BF)2 precursor with organomagnesium imidazole derivative. The N6-coordination polyhedron of the diimidazolyl iron(II) clathrochelate molecule has a distorted trigonal prismatic geometry with the distortion angle φ = 24.1° and the FeN distances approximately 1.91 Å.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 11, Issue 9, September 2008, Pages 988–991