Cyclopentanone thiosemicarbazone (Hcptsc) induces a new bonding pattern in (Ph3P)Cu(μ-Br)(μ3-S,N-Hcptsc)CuBr(PPh3) dimer

Cyclopentanone thiosemicarbazone (Hcptsc) with copper(I) bromide has formed an asymmetric dimer (Ph3P)Cu(μ-Br) (μ3-S,N-Hcptsc)CuBr(PPh3) (1) with a new {Cu(μ-Br)(μ3-S,N)Cu} bonding core.