کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1304911 | 974860 | 2007 | 4 صفحه PDF | دانلود رایگان |

Reaction of SnCl2 with the bisthiosemicarbazone ligand ATSMH2 led to the formation of the octahedral tin(IV) complex [Sn(ATSM)Cl2] (1) comprising one doubly deprotonated ligand occupying the equatorial positions and two axial chlorides. Reaction with SnI4 gave [Sn(ATSM)2] (2), containing two doubly deprotonated ligands giving a distorted dodecahedral geometry. The complexes were characterised by elemental analysis, mass spectrometry, 13C and 119Sn CP/MAS NMR and in the case of complex 2 by X-ray diffraction.
Reaction of SnCl2 with the bisthiosemicarbazone ligand ATSMH2 led to the formation of the octahedral tin(IV) complex [Sn(ATSM)Cl2] (1) comprising one doubly deprotonated ligand occupying the equatorial positions and two axial chlorides. Reaction with SnI4 gave [Sn(ATSM)2] (2), containing two doubly deprotonated ligand giving a distorted dodecahedral geometry.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 10, Issue 6, June 2007, Pages 724–727