کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1304911 974860 2007 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Reactivity of bisthiosemicarbazones with Sn(II) and Sn(IV): The synthesis and structure of an eight-coordinate complex with two bis(thiosemicarbazone) ligands
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Reactivity of bisthiosemicarbazones with Sn(II) and Sn(IV): The synthesis and structure of an eight-coordinate complex with two bis(thiosemicarbazone) ligands
چکیده انگلیسی

Reaction of SnCl2 with the bisthiosemicarbazone ligand ATSMH2 led to the formation of the octahedral tin(IV) complex [Sn(ATSM)Cl2] (1) comprising one doubly deprotonated ligand occupying the equatorial positions and two axial chlorides. Reaction with SnI4 gave [Sn(ATSM)2] (2), containing two doubly deprotonated ligands giving a distorted dodecahedral geometry. The complexes were characterised by elemental analysis, mass spectrometry, 13C and 119Sn CP/MAS NMR and in the case of complex 2 by X-ray diffraction.

Reaction of SnCl2 with the bisthiosemicarbazone ligand ATSMH2 led to the formation of the octahedral tin(IV) complex [Sn(ATSM)Cl2] (1) comprising one doubly deprotonated ligand occupying the equatorial positions and two axial chlorides. Reaction with SnI4 gave [Sn(ATSM)2] (2), containing two doubly deprotonated ligand giving a distorted dodecahedral geometry.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 10, Issue 6, June 2007, Pages 724–727
نویسندگان
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